Final Champion: KJ (Fourth Reign)
| Champion | Defeated | Venue | Location | Date | Reign | Notes |
|---|---|---|---|---|---|---|
| Anna Kournikova (1) | — | XCW Arena | Brackla, Bridgend | 2002-10-27 | 112 days | 1 |
| Tiffani‐Amber Thiessen (1) | — | XCW Arena | Brackla, Bridgend | 2003-02-16 | 2 days | 2 |
| The Kat (1) | Tiffani‐Amber Thiessen | XCW Arena | Brackla, Bridgend | 2003-02-18 | 33 days | |
| Holly Valance (1) | — | XCW Arena | Brackla, Bridgend | 2003-03-23 | 126 days | 3 |
| Lita (1) | Christine | Telewest Arena | Newcastle upon Tyne | 2003-07-27 | 35 days | 4 |
| Annalyse (1) | Lita | Wales National Ice Rink | Cardiff | 2003-08-31 | 28 days | |
| Lita (2) | — | St. David's Hall | Cardiff | 2003-09-28 | 28 days | 5 |
| Christine (1) | — | Jacksonville Veterans Memorial Arena | Jacksonville, FL, USA | 2003-10-26 | 51 days | 6 |
| KJ (1) | — | Millennium Stadium | Cardiff | 2003-12-16 | 124 days | 7 |
| Melissa (1) | KJ | Wales National Ice Rink | Cardiff | 2004-04-18 | # days | 8 |
| Title Change Unknown
KJ (2) wins back the championship. |
||||||
| The Kitten (1) | KJ | XCW Arena Swansea | Swansea | 2004-07-25 | 28 days | |
| Lita (3) | Christine | XCW Arena | Brackla, Bridgend | 2004-08-22 | 35 days | 9 |
| Title Vacated | ||||||
| KJ (3) | Christine | XCW Arena | Brackla, Bridgend | 2004-09-26 | 140 days | 10 |
| Ms. Irresistible (1) | Ms. Sweet | TWF Arena | Brackla, Bridgend | 2005-02-13 | # days | 11 |
| Title Change Unknown
KJ (4) wins back the championship. |
12 | |||||
| # | Notes |
|---|---|
| 1 | Anna Kournikova defeated Carmen Electra and Pamela Anderson in a Three Way match at the first XCW pay-per-view, Halloween Chaos, to become the first champion. |
| 2 | Tiffani‐Amber Thiessen defeated Anna Kournikova, Danni Minogue, and Kylie Minogue in a Four Way Elimination match at XCW Apocalypse to win the championship. |
| 3 | Holly Valance eliminated Anna Kournikova last in a 15‐Women Wet‐T‐Shirt Open Invitational Battle Royal to win the championship at XCW WrestleMadness 3. The other participants in the match were Britney Spears, Christina Aguilera, Christine, Gwyneth Paltrow, Lita, The Kat, Kylie Minogue, Martina Hingis, Pamela Anderson, Stacy Keibler, Tiffani‐Amber Thiessen, Torrie Wilson, & Trish Stratus. |
| 4 | Lita pinned Christine in a Four Way Swimsuit match also involving Annalyse and Holly Valance at XCW One Step Away to win the championship. |
| 5 | Lita won a Three Way Dog Collar match at XCW Sweet Pain also involving Analyse and Christine to win the championship. |
| 6 | At XCW Halloween Chaos II, Christine won a Beauty Pageant to win the championship. The other participants ‐ Annalyse, Holly Valance, Lita, KJ, Stacy Carter ‐ were attacked during the course of proceedings by the Double J's, leaving Christine the only participant able to compete, winning the championship by default. |
| 7 | KJ won a Four Way Santa's Little Helper match also involving Christine, Lita and Melissa during the final episode of Metal in 2003 to win the championship. |
| 8 | Melissa pinned KJ in a Four Way match also involving Christine and Lita at XCW Anarchy Rulz II to win the championship. |
| 9 | Lita pinned Christine in a Four Way match also involving Melissa and The Kitten at XCW Sweet Pain II to win the championship. |
| 10 | Lita falls pregnant with NJS's child and is therefore unable to make title defenses. She vacates the championship at XCW Take No Prisoners II. Her replacement in her title defense was KJ, who pinned Christine to win the championship for a third time. |
| 11 | Ms. Irresistible pinned Ms. Sweet in a Three Way match also involving KJ at xWa Parental Advisory to win the championship. |
| 12 | After XCW officially closes it's doors on October 23, 2005; KJ is recognised as the last XCW Women's Champion. |